南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

CORROSION RESISTANCE OF INTERFERENCE FILM ON STAINLESS STEEL     

张经磊  侯保荣 《中国海洋湖沼学报》1997,15(4):363-368

IwrRODUcrlONStainlessstalhasbeenusedwidelyasbuildingrnateria1,especiallyasdecoratingrnate-rialinbuildings.Ordinarystainlesssteehasonlyonemonot0noussilverywhitCcolourwhichsomeimesdoesnotrnatchwithitSsurmundingenvironment.lnordert0improveitSdereratingperfonnaneeandexpanditsuse,muchresearchhasbeenconductedsincethe4O'st0trytoformabright,uniform,highcorrosi0nandwearresistantco1ourfilmonastainlesssteesurface.Duringtheeariystage,anirnmersionedhodwasused,i.e.inimrs-ingthestainlesssteelinahots0luti…  相似文献   

STRESS CORROSION CRACKING OF AISI 321 STAINLESS STEEL IN ACIDIC SEAWATER     

黄彦良  侯保荣  曹楚南  林海潮 《中国海洋湖沼学报》1997,15(4):373-377

ImooUonONSCCisoneofthemosttwortantcausoffailureofstaiuleSsstalequipmentandfacilitieS.Studiesonunh0refacilitiesshowedthatanaddicchloridesolutionfilmcouldbefo~onthescheeofstalandthatstaiuleSSstalisinaCtivedissolutionstateinaedicchloridesolutionopinetal.,l99O;Gnanamoorthyetal.,l99O).ltisgenerallythoughtxthatSCCcannotoimrwhenthematerialisinaCtiveanodicdissolutionstate,soitsomcewithresultingcasualties(0ldfieldetal.,l99O)arousedattentiont0it.SomeSCCmeCanisrnsproposedpeuang,l988,Newmanctal.,…  相似文献   

EFFECT OF SULPHATE-REDUCING BACTERIA ON ELECTRO-CHEMICAL CORROSION BEHAVIOR OF 16Mn STEEL IN SEA MUD     

张经磊  侯保荣  郭公玉  孙虎元  徐岩 《中国海洋湖沼学报》2001,19(1):87-90

ＩＮＴＲＯＤＵＣＴＩＯＮＩｔｗａｓｇｅｎｅｒａｌｌｙｃｏｎｓｉｄｅｒｅｄｐｒｅｖｉｏｕｓｌｙｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｏｆｓｔｅｅｌｉｎｓｅａｍｕｄｗａｓｎｏｔｓｅｒｉｏｕｓ.Ｈｏｗｅｖｅｒ,ｉｔｗａｓｌａｔｅｒｆｏｕｎｄｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｒａｔｅｏｆｓｔｅｅｌｉｎｓｏｍｅｓｅａｍｕｄｗａｓｈｉｇｈｅｒｔｈａｎｔｈａｔｉｎｓｅａｗａｔｅｒ(Ｋｉｎｇ,1980;Ｓｅｈｍｉｄｅ,1982;Ｇｕｏｅｔａｌ.,1997;Ｈｏｕ,1998).Ｔｈｅｒｅａｒｅｓｏｍｅｒｅｐｏｒｔｓｔｈａｔｔｈｅｃｏｒｒｏｓｉｏｎｒ…  相似文献   

Effect of Inter-Column Spacing on Soil Stresses due to Vibro-Installed Stone Columns: Interesting Findings   总被引：1，自引：0，他引：1  

Hesham Elshazly  Mohamed Elkasabgy  Azza Elleboudy 《Geotechnical and Geological Engineering》2008,26(2):225-236

This paper reveals the interesting relation between the inter-column spacing and the corresponding alteration of soil state of stresses due to the vibro-installation technique. This relation is inferred from analyses for load settlement records of various field load tests, performed for stone columns arrangements with different inter-column spacing values. In order to have adequate confidence in the findings, a well-documented case history, involving three columns patterns along with their relevant field and laboratory test results, is utilized for this study. Moreover, a well-tested finite element model, capable of simulating both elasto-plastic and time dependent soil deformations as well as pore water pressure building and dissipation, is employed in the analysis. Instead of determining the soil response to the test load, based on known initial soil stresses and material properties, the analysis is inversely posed to determine the soil initial stresses, based on the recorded settlements and the post-installation material properties. The alteration in the soil state of stress is represented by the increase in the post-installation horizontal to vertical stress ratio, K*, as a function of the inter-column spacing. It is found that this alteration experiences a systematic decrease in its magnitude as the inter-column spacing increases.  相似文献   

大型桥梁钢沉井下沉过程局部冲刷研究     

高正荣  黄建维  赵晓冬 《海洋工程》2006,24(3):31-35

钢沉井下沉过程中局部冲刷的研究是同类桥墩设计和施工十分关心的重要课题,它对保证钢沉井安全有效施工、桥梁设计中施工期桥墩最大冲深、失稳和安全计算有重要参考价值。通过室内试验研究了钢沉井下沉过程中的局部冲刷机理和冲刷形态,探讨了桥墩下部钢沉井基础施工的相对高程对局部冲刷的变化规律,并将试验研究所获得的局部冲刷规律和影响因素,采用墩型系数方法引入局部冲刷计算中,给出了计算公式。研究成果补充了国家行业规范内容,对同类工程的设计、施工具有借鉴和指导意义。  相似文献   

Calibration of LRFD Format for Steel Jacket Offshore Platforms in China Offshore Area （ 1 ） ： Statistical Parameters of Loads and Resistances     

段忠东周道成  欧进萍 《中国海洋工程》2006,20(1):1-14

1 .IntroductionThe structural design method has evolvedfromthe workingstress method,damage stage methodtolimit state method.The more recent probabilisticlimit state design method,whichis based onreliabili-tytheory,has beengenerallyacceptedinthe designcode…  相似文献   

地震作用下的导管架海洋平台结构动力优化设计研究   总被引：3，自引：1，他引：3  

王兴国  贾默伊周晶 《海洋工程》2003,21(2):16-19

把导管架海洋平台看作钢框架结构，并把优化方法用于结构的抗震设计中；以结构的总重量最小为优化目标，导管的平均直径和壁厚作为设计变量，考虑强度、刚度和稳定等约束条件。通过渤海BZ28—1油田储油平台为例进行了计算，计算结果表明，此方法对海洋平台的设计具有一定的参考意义。  相似文献   

烟台市污水处理深海排放工程设计方案研究与选择   总被引：2，自引：0，他引：2  

王文喜  李明基 《海岸工程》1997,16(1):30-35

沿海城市污水处理深海排放工程在我国起步较晚，烟台市污水处理深海排放工程我国目前规模最大的同类工程，且已进入施工阶段，本文详细阐述了该工程及水工设计方案，在我国城市污水２深海排放工程领域作了积极有益的探索。  相似文献   

沿海新建混凝土建筑的耐久性   总被引：2，自引：1，他引：2  

杨松森  战洪艳  赵铁军 《海岸工程》2002,21(3):66-70

分析了沿海混凝土建筑因耐久性不足而导致破坏的原因，提出了预防措施。  相似文献